14529-33-0 Usage
General Description
1,1,1-trifluoro-3-(2-thienyl)acetone is a synthetic chemical compound with the molecular formula C8H5F3O. It is often used in organic chemistry as a reagent for various chemical reactions. The compound is a liquid with a faint odor, and it is slightly soluble in water but more soluble in organic solvents. 1,1,1-trifluoro-3-(2-thienyl)acetone is known for its strong odor that can cause irritation to the respiratory system if inhaled in large quantities. It is important to handle and store this compound with caution and in accordance with proper safety procedures.
Check Digit Verification of cas no
The CAS Registry Mumber 14529-33-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,5,2 and 9 respectively; the second part has 2 digits, 3 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 14529-33:
(7*1)+(6*4)+(5*5)+(4*2)+(3*9)+(2*3)+(1*3)=100
100 % 10 = 0
So 14529-33-0 is a valid CAS Registry Number.
InChI:InChI=1/C7H5F3OS/c8-7(9,10)6(11)4-5-2-1-3-12-5/h1-3H,4H2
14529-33-0Relevant articles and documents
Highly efficient synthesis of chiral α-CF3 amines via Rh-catalyzed asymmetric hydrogenation
Jiang, Jun,Lu, Wenxin,Lv, Hui,Zhang, Xumu
supporting information, p. 1154 - 1156 (2015/03/14)
Highly enantioselective catalytic asymmetric hydrogenation of α-CF3-enamides has been achieved by employing rhodium-DuanPhos as the catalyst, which provides a readily accessible method for the synthesis of chiral trifluoromethylated amines. The reaction has a broad substrate scope; both aryl- and alkyl-substituted α-CF3-enamides worked smoothly and afford the corresponding chiral amines in high yields and excellent enantioselectivities (up to 99% ee).