145296-99-7Relevant academic research and scientific papers
Homolytic Reactions of Ligated Boranes. Part 17. Amine-Boranes as Polarity Reversal Catalysts for Radical Chain Reactions of Esters with Vinylic Epoxides and with Allylic tert-Butyl Peroxides
Dang, Hai-Shan,Roberts, Brian P.
, p. 891 - 898 (2007/10/02)
In the presence of an amine-borane catalyst, methyl acetate, dimethyl malonate and dimethyl methylmalonate (HZ) each react with 1-methylene-2,3-epoxycyclo-hexanes or -pentanes at a C-H group α to the ester function to give allylic alcohols.The reaction pr
Radical Chain Addition to Vinyl Epoxides Catalysed by Amine-Boranes: Synthesis of Allylic Alcohols
Dang, Hai-Shan,Roberts, Brian P.
, p. 6169 - 6172 (2007/10/02)
In the presence of an amine-borane polarity reversal catalyst, vinyl epoxides react at the α-C-H group of an ester to give allylic alcohols.A free radiacal chain mechanism is followed, involving ring opening of an intermediate oxiranylcarbinyl radical to
