14533-17-6

Basic information

• Product Name: Benzene, 1,1'-(1-chloro-1,3-butadiene-1,4-diyl)bis-, (Z,E)-
• CAS NO: 14533-17-6
• Molecular Formula: C16H13Cl
• Molecular Weight: 240.732
• Mol File: 14533-17-6.mol

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1-chloro-1,3-butadiene-1,4-diyl)bis-, (Z,E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1-chloro-1,3-butadiene-1,4-diyl)bis-, (Z,E)-(14533-17-6)
• EPA Substance Registry System: Benzene, 1,1'-(1-chloro-1,3-butadiene-1,4-diyl)bis-, (Z,E)-(14533-17-6)

Safety Data

• Hazardous Substances Data: 14533-17-6(Hazardous Substances Data)

Upstream product

• 52516-77-5 1-CHLORO-1,4-DIPHENYL-1(Z)-BUTENE 
• 536-74-3 phenylacetylene 
• 100-47-0 benzonitrile 
• 5407-91-0 1,4-diphenylbutan-1-one 
• 102-92-1 Cinnamoyl chloride 
• 1145-92-2 (1SR,2SR)-phenyl(2-phenylcyclopropyl)ketone 
• 41819-40-3 4-chloro-1,4-diphenyl-1-butanone 
• 52516-76-4 (Z)(Z)-1-Brom-4-chlor-1,4-diphenylbuta-1,3-dien 
• 637-59-2 1-Bromo-3-phenylpropane 

Relevant articles and documents

One-step synthesis of 1-halo-1,3-butadienes via ruthenium-catalysed hydrohalogenative dimerisation of alkynes

An efficient, novel and direct access to 1-halo-1,3-butadienes is developed. This stereoselective ruthenium-catalysed reaction proceeds under mild conditions via the head-to-head oxidative coupling of two alkynes and a concomitant hydrohalogenation.

Iridium-catalyzed addition of acid chlorides to terminal alkynes

(Chemical Equation Presented) An iridium N-heterocyclic carbene (NHC) complex, IrCl(cod)(IPr), successfully catalyzed an addition of common aromatic acid chlorides to terminal alkynes to afford (Z)-β-chloro-α,β- unsaturated ketones regio- and stereoselectively. When the NHC ligand (IPr) was changed to a phosphine (RuPhos), the addition occurred with decarbonylation to give the corresponding (Z)-vinyl chlorides. Furthermore, the former reaction using IrCl(cod)(IPr) can be applied to the catalytic synthesis of 2,5-disubstituted furans.

Rhodium-catalyzed reaction of aroyl chlorides with alkynes

Aroyl chlorides react with terminal alkynes accompanied by decarbonylation in the presence of a catalytic amount of [RhCl(cod)]2 and PPh3 to give the corresponding vinyl chloride derivatives regioand stereoselectively in good yields.