1453500-87-2Relevant academic research and scientific papers
Synthesis of Conformationally Restricted Symmetric Macrodiolides via Carbonyl Ylides
Muthusamy, Sengodagounder,Sivaguru, Manickasamy,Suresh, Eringathodi
, p. 2034 - 2042 (2013/07/26)
Reaction of bis-diazocarbonyl compounds and dicarbaldehyde/divinyl derivatives in the presence of rhodium(II) acetate dimer as the catalyst led to the facile synthesis of conformationally restricted symmetric macrodiolides incorporating oxa/dioxa-bridged bicyclic systems. The structure and configuration of a representative macrodiolide were unequivocally confirmed using single-crystal X-ray analysis. Georg Thieme Verlag Stuttgart, New York.
