145351-37-7Relevant academic research and scientific papers
One-Pot Synthesis of Deuterated Aldehydes from Arylmethyl Halides
Li, Xiangmin,Wu, Shanchao,Chen, Shuqiang,Lai, Zengwei,Luo, Hai-Bin,Sheng, Chunquan
, p. 1712 - 1715 (2018)
A facile, one-pot approach for synthesizing deuterated aldehydes from arylmethyl halides was developed using D2O as the deuterium source. The efficient process is realized by a sequence of formation, H/D exchange, and oxidation of pyridinium salt intermediates. The mild and air-compatible reaction conditions enable efficient synthesis of diverse deuterated aldehydes with high deuterium incorporation.
α-(METHYLTHIO)BENZYL SULFONES AS SYNTHETIC INTERMEDIATES. PART V. SYNTHESES OF SOME o- AND m-SUBSTITUTED 1-DEUTERIOBENZALDEHYDES
Wladislaw, B.,Marzorati, L.,Ebeling, G.
, p. 25 - 28 (2007/10/02)
o- and m-Substituted α-methylthiobenzyl sulfones incorporate deuterium when treated with a base and deuterium oxide.The resulting deuterated sulfones, by thermal decomposition, afford o- and m-substituted 1-deuteriobenzaldehydes in good yields and high is
