145388-13-2

Basic information

• Product Name: 3-(3-nitrophenyl)-1-phenyl-3-phenylsulphanylpropan-1-one
• CAS NO: 145388-13-2
• Molecular Weight: 363.437
• Mol File: 145388-13-2.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 3-(3-nitrophenyl)-1-phenyl-3-phenylsulphanylpropan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(3-nitrophenyl)-1-phenyl-3-phenylsulphanylpropan-1-one(145388-13-2)
• EPA Substance Registry System: 3-(3-nitrophenyl)-1-phenyl-3-phenylsulphanylpropan-1-one(145388-13-2)

Safety Data

• Hazardous Substances Data: 145388-13-2(Hazardous Substances Data)

Upstream product

• 99-61-6 3-nitro-benzaldehyde 
• 98-86-2 acetophenone 
• 614-48-2 3-nitrochalcone 
• 108-98-5 thiophenol 
• 614-48-2 (E)-3-nitrochalcone 

Downstream Products

• 3814-20-8 4-mercaptoacetophenone 

Relevant articles and documents

Desulfurative Chlorination of Alkyl Phenyl Sulfides

The chlorination of readily available secondary and tertiary alkyl phenyl sulfides using (dichloroiodo)benzene (PhICl2) is reported. This mild and rapid nucleophilic chlorination is extended to sulfa-Michael derived sulfides, affording elimination-sensitive β-chloro carbonyl and nitro compounds in good yields. The chlorination of enantioenriched benzylic sulfides to the corresponding inverted chlorides proceeds with high stereospecificity, thus providing a formal entry into enantioenriched chloro-Michael adducts. A mechanism implying the formation of a dichloro-λ4-sulfurane intermediate is proposed.

Ionic-liquid-supported 1,5,7-triazabicyclo[4.4.0]dec-5-ene - An efficient and recyclable organocatalyst for Michael addition to α,β-unsaturated ketones

A novel ionic-liquid-supported 1,5,7-triazabicyclo[4.4.0]dec-5-ene (IL-TBD) was synthesized and investigated for its ability to act as an active organocatalyst in the Michael addition of active methylene compounds and thiophenols to chalcones under solven

A mild and highly efficient one-pot three-component reaction for carbon-sulfur bond formation catalyzed by potassium tert-butoxide

Potassium tert-butoxide has been found to be a highly efficient catalyst for one-pot, three-component reaction of aryl aldehydes, acetophenones, and thiols via Claisen-Schmidt/Michael addition reactions for the synthesis of thia-Michael adducts in high yields. The reactions are best carried out in tert-butyl alcohol at room temperature.