145417-01-2

Basic information

• Product Name: 2-pyridyl 3,5-di-O-benzoyl-2-deoxy-1-thio-α,β-D-ribofuranoside
• Synonyms: 2-pyridyl 3,5-di-O-benzoyl-2-deoxy-1-thio-α,β-D-ribofuranoside
• CAS NO: 145417-01-2
• Molecular Weight: 435.5
• Mol File: 145417-01-2.mol

Chemical Properties

• CAS DataBase Reference: 2-pyridyl 3,5-di-O-benzoyl-2-deoxy-1-thio-α,β-D-ribofuranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 2-pyridyl 3,5-di-O-benzoyl-2-deoxy-1-thio-α,β-D-ribofuranoside(145417-01-2)
• EPA Substance Registry System: 2-pyridyl 3,5-di-O-benzoyl-2-deoxy-1-thio-α,β-D-ribofuranoside(145417-01-2)

Safety Data

• Hazardous Substances Data: 145417-01-2(Hazardous Substances Data)

Upstream product

• 145416-96-2 1,3,5-tri-O-benzoyl-2-deoxy-D-ribofuranose 
• 51785-70-7 methyl 3,5-dibenzoyloxy-2-deoxy-β-D-erythropentofuranoside 
• 82462-50-8 2,5-anhydro-4,6-di-O-benzoyl-3-deoxy-D-arabino-hexonic acid 
• 127676-66-8 C₂₀H₁₇NO₅ 
• 452-51-7 D-2-deoxyribose 
• 2127-03-9 2,2'-dipyridyldisulphide 
• 95041-53-5 3,5-Di-O-benzoyl-2-desoxy-D-ribose 

Downstream Products

• 55734-51-5 1,4-anhydro-2-deoxy-3,5-di-O-benzoyl-D-erythro-pent-1-enitol 
• 140186-59-0 methyl 2,3-di-O-benzyl-6-O-(3,5-di-O-benzoyl-2-deoxy-α-D-ribofuranosyl)-α-D-glucopyranoside 
• 140186-58-9 1,2:5,6-di-O-isopropylidene-3-O-(3,5-di-O-benzoyl-2-deoxy-α-D-ribofuranosyl)-α-D-glucofuranoside 
• 140186-57-8 1,2:3,4-di-O-isopropylidene-5-O-(3,5-di-O-benzoyl-2-deoxy-α-D-ribofuranosyl)-α-D-galactopyranoside 
• 140186-56-7 methyl 2,3-O-isopropylidene-5-O-(3,5-di-O-benzoyl-2-deoxy-α-D-ribofuranosyl)-α-D-ribofuranoside 

Relevant articles and documents

Stereoselective synthesis of α-linked 2-deoxysaccharides and furanosaccharides by the use of 2-deoxy 2-pyridyl-1-thio pyrano- and furanosides as donors and methyl iodide as an activator

A practical and highly stereoselective glycosidation methodology is described, where anomeric mixture of 2-deoxy 2-pyridyl-1-thiopyranoside donors (1-3,27) have been coupled with several sugar alcohols (4-8,29,31) on activation by methyl iodide to obtain axially linked 2-deoxysaccharides (9-17,30,32,33). Application of this method for the synthesis of disaccharide fragment 28 of avermectin is also described. Utility of this method is also shown by use of 2-pyridyl-1-thiofuranosides (34-36) as donors to prepare α-linked furanosides (42-51).

A Facile Preparative Method of C-Nucleosides

Facile and general preparative method of C-nucleosides has been achieved via 4 steps starting from 2-deoxy-D-ribose.The essential step in this method is the use of radical coupling reaction of 2-deoxy-D-ribofuranosyl radical derivative and some heteroaromatic bases.