1454597-85-3Relevant academic research and scientific papers
A convergent and stereoselective synthesis of the glycolipid components phthioceranic acid and hydroxyphthioceranic acid
Pischl, Matthias C.,Weise, Christian F.,Mueller, Marc-Andre,Pfaltz, Andreas,Schneider, Christoph
, p. 8968 - 8972 (2013)
Simply convergent: The polydeoxypropionates 1 and 2 are important constituents of the cell wall of Mycobacterium tuberculosis. Key steps in their total synthesis include two Suzuki-Miyaura cross-coupling reactions and two highly diastereoselective iridium-catalyzed hydrogenations. The trideoxypropionates employed as central building blocks were prepared by sequential oxy-Cope rearrangement, hydrogenation, and enolate methylation. Copyright
