1454711-10-4Relevant articles and documents
Asymmetric synthesis of the C1-C6 portion of the psymberin using an Evans chiral auxiliary
Pal, Ashutosh,Peng, Zhenghong,Schuber Jr., Paul T.,Bhanu Prasad, Basvoju A.,Bornmann, William G.
, p. 5555 - 5557 (2013)
The C1-C6 region of the potent cytotoxic agent psymberin has been synthesized. The key transformations of the synthesis are an auxiliary-controlled addition of a Sn(II)-glycolate enolate to an aldehyde to yield the anti-aldol product and transforming the