14561-55-8Relevant academic research and scientific papers
SYNTHESIS OF ω-HYDROXY ANALOGUES OF VALINE, LEUCINE AND ISOLEUCINE
Englisch-Peters, Sabine
, p. 6127 - 6134 (2007/10/02)
The isomers of γ-hydroxy-valine (6) were prepared by a modified Erlenmeyer synthesis and the δ-hydroxy analogues each of leucine (16a) and isoleucine (16b) were synthesized via 1,4-Michael addition.The diastereomers of 6 could be separated by column chrom
FLAME-INDUCED CARBOXYLATION OF UNSATURATED AMINES IN AN AQUEOUS FORMIC ACID SOLUTION
Nomoto, Shinya,Harada, Kaoru
, p. 145 - 148 (2007/10/02)
When a hydrogen-oxygen flame was kept in contact with an aqueous formic acid solution of unsaturated amines, carboxylation onto a double bond took place.This reaction revealed to be initiated by addition of a hydrogen atom to the double bond followed by coupling of the resulted substrate radical with a carboxyl radical.
