145653-05-0

Basic information

• Product Name: (E)-4-cyclohexyl-4-diphenylphosphinoylbut-2-en-1-ol
• Synonyms: (E)-4-cyclohexyl-4-diphenylphosphinoylbut-2-en-1-ol
• CAS NO: 145653-05-0
• Molecular Weight: 354.429
• Mol File: 145653-05-0.mol

Chemical Properties

• CAS DataBase Reference: (E)-4-cyclohexyl-4-diphenylphosphinoylbut-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4-cyclohexyl-4-diphenylphosphinoylbut-2-en-1-ol(145653-05-0)
• EPA Substance Registry System: (E)-4-cyclohexyl-4-diphenylphosphinoylbut-2-en-1-ol(145653-05-0)

Safety Data

• Hazardous Substances Data: 145653-05-0(Hazardous Substances Data)

Upstream product

• 145652-98-8 4-cyclohexyl-4-diphenylphosphinoylbut-1-en-3-yl acetate 
• 145653-02-7 (E)-4-cyclohexyl-4-diphenylphosphynoylbut-2-en-1-yl acetate 
• 88533-61-3 cyclohexylmethyldiphenylphosphine oxide 

Downstream Products

• 148406-92-2 (2R,3R)-3-[(R)-Cyclohexyl-(diphenyl-phosphinoyl)-methyl]-oxirane-2-carboxylic acid 
• 145681-43-2 (E)-(R)-4-Cyclohexyl-4-(diphenyl-phosphinoyl)-but-2-en-1-ol 
• 145653-24-3 {(2R,3S)-3-[(R)-Cyclohexyl-(diphenyl-phosphinoyl)-methyl]-oxiranyl}-methanol 
• 145653-24-3 {(2S,3R)-3-[(S)-Cyclohexyl-(diphenyl-phosphinoyl)-methyl]-oxiranyl}-methanol 
• 145681-31-8 {(2S,3R)-3-[(R)-Cyclohexyl-(diphenyl-phosphinoyl)-methyl]-oxiranyl}-methanol 

Relevant articles and documents

The Synthesis of δ-Hydroxy Allylic Phosphine Oxides by Palladium(II)-catalysed Allylic Acetate Transposition

Palladium(II)-catalysed allylic acetate transposition, when driven by the diphenylphosphinoyl (Ph2PO) group, is regiospecific (acetate moves away from the Ph2PO group), stereoselective (the new double bond is E), and stereospecific (the acetate moves supr

The Synthesis of δ-Hydroxy Allylic Phosphine Oxides by Palladium(II)-Catalysed Allylic Transposition

Palladium(II)-catalysed rearrangement of allylic acetates 5, which contain a diphenylphosphinoyl group, yields transposed acetates 6 in good yield.The reaction is mild, general for most substitution patterns, and stereospecific.The transposed acetates 6 m