145655-39-6Relevant articles and documents
Utility of Phosphonium-Substituted Ester Enolates as Synthetic Intermediates. A Novel Trialkylphosphine-Catalyzed Rearrangement of Allylic Acrylates
Hanamoto, Takeshi,Baba, Yoshiyasu,Inanaga, Junji
, p. 299 - 300 (2007/10/02)
A novel Ireland-type rearrangement which utilizes a catalytic amount of a trialkylphosphine with allylic acrylates has been developed as a synthetic entry into α-methylene-γ,δ-unsaturated carboxylic acids.