1456718-87-8

Basic information

• Product Name: methyl 2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-4-O-(2'-naphthyl)methyl-α-D-glucopyranoside
• Synonyms: methyl 2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-4-O-(2'-naphthyl)methyl-α-D-glucopyranoside
• CAS NO: 1456718-87-8
• Molecular Weight: 620.764
• Mol File: 1456718-87-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-4-O-(2'-naphthyl)methyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-4-O-(2'-naphthyl)methyl-α-D-glucopyranoside(1456718-87-8)
• EPA Substance Registry System: methyl 2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-4-O-(2'-naphthyl)methyl-α-D-glucopyranoside(1456718-87-8)

Safety Data

• Hazardous Substances Data: 1456718-87-8(Hazardous Substances Data)

Upstream product

• 1590421-87-6 methyl 2,3-di-O-benzyl-6-deoxy-6-iodo-4-O-(2'-naphthyl)methyl-α-D-glucopyranoside 
• 62-50-0 Ethyl methanesulfonate 
• 291314-27-7 methyl 2,3-di-O-benzyl-4-O-(2-naphthyl)methyl-α-D-glucopyranoside 

Downstream Products

• 1590421-89-8 methyl 2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranoside 
• 1590422-04-0 methyl [2-O-acetyl-4,6-O-(benzylidene)-3-O-methyl-α-L-idopyranosyl]-(1→4)-2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranoside 
• 1590422-06-2 methyl [2-O-acetyl-3-O-methyl-α-L-idopyranosyl]-(1→4)-2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranoside 
• 1590422-07-3 methyl [methyl (2-O-acetyl-3-O-methyl-α-l-idopyranosyl)uronate]-(1→4)-2,3-di-O-benzyl-6-deoxy-6-C-(ethyl sulfonatomethyl)-α-D-glucopyranoside 

Relevant articles and documents

Large-scale synthesis of 6-deoxy-6-sulfonatomethyl glycosides and their application for novel synthesis of a heparinoid pentasaccharide trisulfonic acid of anticoagulant activity

Multigram-scale syntheses of three 6-deoxy-6-sulfonatomethyl α-glucosides were accomplished via reactions of the corresponding primary triflate derivatives with the lithiated ethyl methanesulfonate. Chemoselective glycosylation reactions of different 6-C-sulfonatomethyl glucoside donors were studied. The sulfonic acid-containing building blocks were utilised in a novel [2+3] block synthesis of a trisulfonic acid isoster of the anticoagulant pentasaccharide idraparinux.