14568-86-6Relevant academic research and scientific papers
POLYMERIZABLE MONOMER, COMPOSITION, CURABLE COMPOSITION AND RESIN MEMBER
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Paragraph 0095, (2016/10/07)
PROBLEM TO BE SOLVED: To provide: a (meth)acrylate-based polymerizable monomer which allows compatibility with various materials to be easily secured and provides a small value of (polymerization shrinkage rate)/(hardness of a cured product); and a material using the same. SOLUTION: The present invention provides a polymerizable monomer represented by general formula (1), a composition using the same, a curable composition and a resin member. [X is a divalent group; Y and Z are (meth)acroyloxy-L-OCHR1- (R1 is H or a C1-6 alkyl group as a monovalent group; and L is a hydrocarbon group whose main chain has 2-50 carbon atoms); Ar1 and Ar2 are aromatic groups; o and p are integers selected from the range from 1 to 3; and m and n are each 0 or 1. Here, if m=0, then Y and Ar2 are directly coupled; and if n=0, then Ar1 and Ar2 are directly coupled.] COPYRIGHT: (C)2016,JPO&INPIT
The Synthesis of Precisely Structured Polyurethanes. Part 1. Monomer Synthesis
Denholm, Alistair A.,George, Maurice H.,Hailes, Helen C.,Tiffin, Peter J.,Widdowson, David A.
, p. 541 - 548 (2007/10/02)
The synthesis of a series of bifunctional siloxymethyl isocyanate monomers, required for the solid phase synthesis of structurally defined polyurethane oligomers and copolymers is described.Thus, the MDI mimics 2, 3 were synthesised via a desymmetrisation
A Convenient Synthesis of MacrocyclicParacyclophanes
Gruetzmacher, Hans-Friedrich,Mehdizadeh, Ahmed,Muelverstedt, Astrid
, p. 1163 - 1166 (2007/10/02)
The paracyclophanedienes 9-11 were prepared in good yields by a McMurry cyclization of the bis(4-acylphenyl)methanes 5 and 6 and of bis(4-acetylphenyl) ether (7), respectively. - Key Words: Cyclophanes / Coupling reaction / McMurry reaction
