1456813-65-2Relevant academic research and scientific papers
Stereoselective synthesis, structural aspects, and NMR properties of stable C-fluorinated phosphaalkenes
Ito, Shigekazu,Nakagawa, Takeshi,Mikami, Koichi
supporting information, p. 9221 - 9223 (2013/09/24)
We report a stereoselective route to synthesize (E)-2-bromo-2-fluoro-1-(2, 4,6-tri-t-butylphenyl)-2-phosphaethene. Configurationally and conformationally controlled 2-fluoro-1-phosphaethene [Mes*PC(F)H; Mes* = 2,4,6-tBu3C6H2] and 2-fluoro-1,3- diphosphapropene [Mes*PC(F)-PPh2] were synthesized and the NMR data, including relaxation parameters, were collected.
