145745-77-3

Upstream product

• 145745-75-1 (Z)-methyl 2-diethoxymethyl-3-dimethyl(phenyl)silylprop-2-enoate 
• 145745-76-2 (E)-2-Diethoxymethyl-3-(dimethyl-phenyl-silanyl)-prop-2-en-1-ol 
• 119481-06-0 (E)-2-hydroxymethyl-2-[(dimethylphenylsilyl)methylene]ethanal 
• 145746-07-2 (E)-methyl 3-dimethyl(phenyl)silyl-2-hydroxymethylprop-2-enoate 
• 10160-87-9 Propiolaldehyde diethyl acetal 
• 3839-31-4 dimethyl(phenyl)silyllithium 

Downstream Products

• 138175-73-2 (1R,3aR,4R,8bR)-1-[2-(2,2-Dimethoxy-ethyl)-[1,3]dithian-2-yl]-4-(dimethyl-phenyl-silanyl)-1,4,5,7,8,8b-hexahydro-benzo[1,2-b;3,4-c']difuran-3a-carboxylic acid methyl ester 
• 138175-74-3 C₂₆H₃₆O₆S₂Si 
• 138175-74-3 C₂₆H₃₆O₆S₂Si 
• 138175-75-4 C₃₆H₅₂O₈S₂Si 
• 138175-76-5 C₃₆H₅₄O₈S₂Si 
• 138175-79-8 C₂₇H₃₂O₈ 
• 138175-80-1 (2aS,3R,5S,5aR,8S,8aR,8bR)-methyl 3,5-<(R)-benzylidenedioxy>-8-tert-butyldimethylsiloxy-5a-(2'-hydroxyethyl)-4,5,5a,8,8a,8b-hexahydro-2H,3H-naphtho<1,8-bc>furan-2a-carboxylate 
• 138175-77-6 (2aR,3R,5S,5aR,8aR,8bR)-3-(Dimethyl-phenyl-silanyl)-5a-[2-(2,2-dimethyl-propionyloxy)-ethyl]-5-hydroxy-8-oxo-4,5,5a,8,8a,8b-hexahydro-3H-naphtho[1,8-bc]furan-2a-carboxylic acid methyl ester 
• 138175-81-2 (2aS,3R,5S,5aS,8S,8aR,8bR)-methyl 3,5-<(R)-benzylidenedioxy>-8-tert-butyldimethylsiloxy-5a-formyl-4,5,5a,8,8a,8b-hexahydro-2H,3H-naphtho<1,8-bc>furan-2a-carboxylate 
• 138175-83-4 (2aR,4aR,5RS,8aR,9S,11R,11aS,11bS)-methyl 9,11-<(R)-benzylidenedioxy>-5-cyano3,6-dioxoperhydrofuro<2',3',4';4,5>naphtho<8a,1-c>pyran-11a-carboxylate 
• 138175-73-2 (1R*,3aS*,4S*,8bR*)-methyl 1-<2'-(2'',2''-dimethoxyethyl)-1',3'-dithian-2'-yl>-4-dimethyl(phenyl)silyl-1,4,5,7,8,8b-hexahydro-3H-benzo<1,2-b:3,4-c'>difuran-3a-carboxylate 
• 138175-73-2 (1R*,3aR*,4R*,*8bR*)-methyl 1-<2'-(2'',2''-dimethoxyethyl)-1',3'-dithian-2'-yl>-4-dimethyl(phenyl)silyl-1,4,5,7,8,8b-hexahydro-3H-benzo<1,2-b:3,4-c'>difuran-3a-carboxylate 
• 138175-87-8 (E)-methyl 2-<1'-<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>-2'-<(Z)-2''''-oxotetrahydrofuran-3-ylidene>ethoxymethyl>-3-dimethyl(phenyl)silylprop-2-enoate 
• 145745-81-9 (E)-methyl 2-<<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>(formyl)ethoxymethyl>-3-dimethyl(phenyl)silylprop-2-enoate 

Relevant academic research and scientific papers

The application of a monolithic triphenylphosphine reagent for conducting Ramirez gem-dibromoolefination reactions in flow

The application of a monolithic form of triphenylphosphine to the Ramirez gem-dibromoolefination reaction using flow chemistry techniques is reported. A variety of gem-dibromides were synthesised in high purity and excellent yield following only removal of solvent and no further off-line purification. It is also possible to perform the Appel reaction using the same monolith and the relationship between the mechanisms of the two reactions is discussed.

Chemistry of Insect Antifeedants from Azadirachta indica (Part 12): Use of Silicon as a Control Element in the Synthesis of a Highly Functionalized Decalin Fragment of Azadirachtin

A diastereoselective synthesis of a highly functionalized decalin fragment 61 of the insect antifeedant azadirachtin 1 is described.An intramolecular Diels-Alder reaction of triene 15 and subsequent intramolecular aldol reaction were employed to assemble

Chemistry of insect antifeedants from Azadirachta Indica (Part 10): Synthesis of a highly functionalised decalin fragment of azadirachtin

The synthesis of a highly functionalised decalin fragment (2) of the antifeedant azadirachtin (1) is described. A silyl group was employed to control the stereoselectivity of several key steps and to introduce C3 hydroxyl functionality. A novel ring contr