119481-06-0Relevant academic research and scientific papers
An efficient procedure for the preparation of chiral β-substituted (E)-crotylsilanes: Application of a rhodium(II) catalyzed silylformylation of terminal alkynes
Jain,Jain, Nareshkumar F.,Cirillo,Cirillo, Pier F.,Schaus,Schaus, Jennifer V.,Panek,Panek, James S.
, p. 8723 - 8726 (2007/10/02)
Functionalized β-substituted (E)-crotylsilanes (R)-7 and (S)-8, bearing an alkyl or aryl group adjacent to the stereogenic C-Si center have been synthesized in an efficient four-step procedure initiated with a regio- and stereoselective silylformylation o
Chemistry of Insect Antifeedants from Azadirachta indica (Part 12): Use of Silicon as a Control Element in the Synthesis of a Highly Functionalized Decalin Fragment of Azadirachtin
Kolb, Hartmuth C.,Ley, Steven V.,Slawin, Alexandra M. Z.,Williams, David J.
, p. 2735 - 2762 (2007/10/02)
A diastereoselective synthesis of a highly functionalized decalin fragment 61 of the insect antifeedant azadirachtin 1 is described.An intramolecular Diels-Alder reaction of triene 15 and subsequent intramolecular aldol reaction were employed to assemble
