145747-27-9Relevant academic research and scientific papers
Lipase-catalysed selective deacetylation of phenolic/enolic acetoxy groups in peracetylated benzyl phenyl ketones
Parmar, Virinder S.,Pati, Hari N.,Azim, Abul,Kumar, Rajesh,Himanshu,Bisht, Kirpal S.,Prasad, Ashok K.,Errington, William
, p. 109 - 118 (2007/10/03)
Highly chemo- and regioselective de-esterification has been observed in the deacetylation of peracetylated enolic forms of polyphenolic benzyl phenyl ketones by lipase from porcine pancreas (PPL) suspended in tetrahydrofuran (THF). The enzyme selectively
Regioselective hydrolysis of polyacetoxy aromatic ketones with lipases in organic solvents
Parmar, V S,Khanduri, C H,Tyagi, O D,Prasad, A K,Gupta, Suman,et al.
, p. 925 - 929 (2007/10/02)
Lipases from porcine pancreas (PPL) and Candida cylindracea (CCL) have been used for deacetylation of polyacetoxy aromatic ketones in organic solvents.A systematic study has been made to establish regioselectivity, effect of the nature of solvents and role of steric bulk on hydrolysable groups.High regioselectivity and effect of nature of solvents on the rate of the reactions have been observed.
