14575-90-7

Upstream product

• 24041-60-9 (+)-isopinocampheol 
• 98-59-9 p-toluenesulfonyl chloride 
• 2734-31-8 (1R,2R,3S,5S)-(+)-neoisopinocampheol 
• 51152-11-5 (1R*,2R*,3R*,5S*)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-ol 
• 1196-00-5 (+)-isopinocampheol 

Downstream Products

• 7785-70-8 (+)-α-pinene 
• 24031-99-0 (-)-trans-δ-pinene 
• 24031-98-9 (1S,4S,5R)-4,6,6-trimethylbicyclo[3.1.1]hept-2-ene 
• 1000304-40-4 (1S,2S,5R,6S,7S)-6,8,8-trimethyl-3-azatricyclo[5.1.1.0^2,5]nonan-4-one 
• 1462351-80-9 (1S,2S,3R,5R)-(-)-(Z)-cinnamyl pinocamphyl selenide 
• 1462351-79-6 (1S,2S,3R,5R)-(+)-(E)-cinnamyl pinocamphyl selenide 
• 104713-12-4 (R)-1-phenylprop-2-en-1-ol 
• 104713-12-4 (1S)-1-phenylprop-2-en-1-ol 
• 80-56-8 Pinene 
• 79-92-5 camphene 
• 14576-08-0 4-(2-methoxypropan-2-yl)-1-methylcyclohex-1-ene 
• 38988-92-0 pinan-2β-yl methyl ether 
• 38988-92-0 pinan-2α-yl methyl ether 
• 138-86-3 limonene. 

Relevant academic research and scientific papers

Stereoselective propene polymerization at a metallocene/alumoxane catalyst derived from the chrally-substituted "meso-like" (p-R, p-S)-bis-zirconium dichloride

Isopinocamphyl-tosylate (2) was treated with indenyllithium to yield 3-(neoisopinocamphyl)-indene (3).Treatment of 3 with methyllithium gave 1-(neoisopinocamphyl)indenyllithium (4) which was then treated with 0.5 molar equivalents of ZrCl4(thf)2 to give a

Regio- and stereoselective synthesis of the enantiomers of monoterpene-based β-amino acid derivatives

The regio- and stereospecific addition of chlorosulfonyl isocyanate to cis-δ-pinene enantiomers has furnished monoterpene-fused β-lactams. The observed regioselectivity can be explained by ab initio DFT modeling of transition state structures. In contrast with the less reactive α-pinane-fused β-lactam 4, the resulting β-lactams 5 and 13 containing an amino group connected to a secondary carbon possess similar reactivity to the cycloalkane-fused analogues and can be easily converted to the β-amino acid and its protected derivatives. The base-catalyzed isomerization of the cis-amino ester afforded the corresponding trans-amino ester in moderate yield.

Rearrangement of Pinane Derivatives. Part 8. Deamination of 2αH-Pinan-3α-ylamine

Solvolysis of 2αH-pinan-3α-yl toluene-p-sulphonate has been shown to proceed with concomitant 1,2-hydride shift to give the pinan-2-yl carbocation.Contrary to earlier reports, this species reacts normally to give, in good yield, pinan-2-yl substitution products.In contrast the pinan-3-ylamines react via a similar route, but give much smaller amounts of pinan-2-yl products.The usual reasons for differences between solvolysis and deamination (i.e. the intermediacy of diazonium ions and/or high-energy ions) can be discounted, and possible reasons for the differences in behaviour are discussed.