145782-24-7Relevant articles and documents
Two-faced reactivity of alkenes: cis- versus trans-aminopalladation in aerobic Pd-catalyzed intramolecular Aza-Wacker reactions
Liu, Guosheng,Stahl, Shannon S.
, p. 6328 - 6335 (2007)
A number of different PdII catalyst systems have been reported recently for the Wacker-type aerobic oxidative cyclization of alkenes bearing tethered nitrogen nucleophiles. This study examines the stereochemistry of the aminopalladation step wi
Intramolecular aminopalladation and cross coupling of acetylenic amines
Luo, Fen-Tair,Wang, Ren-Tzong
, p. 6835 - 6838 (2007/10/02)
Stereodefined 2-alkylidene-pyrrolidines and -piperidine were synthesized by treatment of an acetylenic amines with n-BuLi followed by addition of catalytic amount of Pd(OAc)2 and PPh3 in THF and 3 equiv of an organic halide.