940909-11-5

Upstream product

• 591-50-4 iodobenzene 
• 100-42-5 styrene 
• 81097-24-7 N-tosyl-(4-pentenyl)amine 
• 122333-71-5 trans-5-phenyl-4-penten-1-amine 
• 98-59-9 p-toluenesulfonyl chloride 
• 30154-22-4 trans-5-phenyl-4-pentenamide 
• 22768-07-6 (E)-ethyl 5-phenylpent-4-enoate 
• 99858-43-2 5-phenylpent-4-enylamine 
• 24595-58-2 5-phenylpent-4-yn-1-ol 
• 5390-04-5 pent-1-yn-5-ol 
• 13159-16-5 (E)-5-phenyl-4-penten-1-ol 
• 70-55-3 toluene-4-sulfonamide 

Downstream Products

• 145782-24-7 2-[1-Phenyl-meth-(E)-ylidene]-1-(toluene-4-sulfonyl)-pyrrolidine 
• 1613582-38-9 (2R,3S)-N-(4-toluenesulfonyl)-2-phenyl-3-(phenylthio)piperidine 
• 1613582-39-0 (2S,3R)-N-(4-toluenesulfonyl)-2-phenyl-3-(phenylthio)piperidine 
• 1323723-24-5 (R)-2-phenyl-N-(4-toluenesulfonyl)piperidine 
• 1392282-92-6 (S)-2-phenyl-N-(4-toluenesulfonyl)piperidine 
• 176650-38-7 2-phenyl-1-(toluene-4-sulfonyl)-piperidine 
• 1011246-92-6 2-benzyl-1-(toluene-4-sulfonyl)pyrrolidine 
• 1318240-03-7 N-tosyl-2-benzoylpyrrolidine 

Relevant academic research and scientific papers

Bis(trifluoromethanesulfonimide) (BSI): Acidity and application to hydrofunctionalization as a Br?nsted acid catalyst

A binaphthyl derivative, bearing bis(trifluoromethanesulfonimide) (BSI) moiety, was developed as a novel Br?nsted acid. Computational prediction of the pKa value of BSI indicated its classification as a strong Br?nsted acid. BSI catalyzed the h

Arene Trifunctionalization with Highly Fused Ring Systems through a Domino Aryne Nucleophilic and Diels–Alder Cascade

A convenient and efficient domino aryne process was developed under transition-metal-free conditions to generate a range of tetra- and pentacyclic ring systems. This transformation was realized via a 1,2-benzdiyne through a nucleophilic and Diels–Alder reaction cascade using styrene as the diene moiety. Three new chemical bonds, namely one C?N and two C?C bonds, and two benzofused rings could be constructed concomitantly, which was made possible by distinct chemoselective control at both the 1,2-aryne and 2,3-aryne stages. Moreover, in-depth studies were carried out on the domino aryne precursors and controlling the diastereoselectivity.

Lewis base catalyzed, enantioselective, intramolecular sulfenoamination of olefins

A method for the enantioselective, intramolecular sulfenoamination of various olefins has been developed using a chiral BINAM-based selenophosphoramide, Lewis base catalyst. Terminal and trans disubstituted alkenes afforded pyrrolidines, piperidines, and

Two-faced reactivity of alkenes: cis- versus trans-aminopalladation in aerobic Pd-catalyzed intramolecular Aza-Wacker reactions

A number of different PdII catalyst systems have been reported recently for the Wacker-type aerobic oxidative cyclization of alkenes bearing tethered nitrogen nucleophiles. This study examines the stereochemistry of the aminopalladation step wi