14579-59-0Relevant academic research and scientific papers
INTERMOLECULAR C-H SILYLATION OF UNACTIVATED ARENES
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Paragraph 00131, (2015/03/28)
Reaction mixtures for silvlating arene substrates and methods of using such reaction mixtures to silyiate the arene substrates are provided. Exemplary reaction mixtures include the arene substrate, a liganded metal catalyst, a hydrogen acceptor and an organic solvent. The reaction conditions allow for diverse substituents on the arene substrate.
Mechanism of the rhodium-catalyzed silylation of arene C-H bonds
Cheng, Chen,Hartwig, John F.
supporting information, p. 12064 - 12072 (2014/10/16)
Mechanistic studies on the rhodium-catalyzed silylation of arene C-H bonds are reported. The resting state of the catalyst was fully characterized by NMR spectroscopy and X-ray diffraction and was determined to be a phosphine-ligated Rh(III) silyl dihydri
