145799-40-2

Basic information

• Product Name: methyl (S,S-trans)-4-(3-benzyloxymethyloxiran-2-yl)butanoate
• CAS NO: 145799-40-2
• Molecular Weight: 264.321
• Mol File: 145799-40-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (S,S-trans)-4-(3-benzyloxymethyloxiran-2-yl)butanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (S,S-trans)-4-(3-benzyloxymethyloxiran-2-yl)butanoate(145799-40-2)
• EPA Substance Registry System: methyl (S,S-trans)-4-(3-benzyloxymethyloxiran-2-yl)butanoate(145799-40-2)

Safety Data

• Hazardous Substances Data: 145799-40-2(Hazardous Substances Data)

Upstream product

• 145799-34-4 (+/-)-2,2-dimethyl-6-(2-hydroxybut-3-enyl)-1,3-dioxin-4-one 
• 145799-38-8 (1'R,6S)-6-(2'-benzyloxy-1'-tosyloxyethyl)-4-tosyloxy-5,6-dihydropyran-2-one 
• 145799-36-6 (2'S,3'R)-6-(4'-benzyloxy-2',3'-dihydroxybutyl)-2,2-dimethyl-1,3-dioxin-4-one 
• 145799-37-7 (1'R,6S)-6-(2'-benzyloxy-1'-hydroxyethyl)-5,6-dihydropyran-2(3H),4-dione 
• 145799-35-5 (2'S,3'R)-6-(3',4'-epoxy-2'-hydroxybutyl)-2,2-dimethyl-1,3-dioxin-4-one 
• 130573-43-2 (2,2-dimethyl-6-methylene-6H-1,3-dioxin-4-yloxy)trimethylsilane 
• 67-56-1 methanol 
• 145799-39-9 (1'R,6S)-6-(2'-benzyloxy-1'-tosyloxyethyl)tetrahydropyran-2-one 

Downstream Products

• 73957-99-0 (-)-(S,S-trans)-3-(hydroxymethyl)oxiranebutanoic acid methyl ester 

Relevant articles and documents

Use of 1,3-Dioxin-4-ones and Related Compounds in Synthesis. Part 39. Enantioselective Synthesis of 1,3-Dioxin-4-ones Having 2,3-Dihydroxy- or 2,3,4-Trihydroxyalkyl Groups at the 6-Position: Versatile Building Blocks of Polyhydroxylated 4-7 Carbon Backbones

1,3-Dioxin-4-ones having 3-hydroxyprop-1-enyl and 2-hydroxybut-3-enyl groups at the 6-position afford, after the Sharpless asymmetric epoxidation followed by epoxide ring cleavage, the 6-- and 6-dioxinones.The former acts as a four- and six-carbon building block, while the latter as a five- and seven-carbon building block.