145910-08-3Relevant academic research and scientific papers
A NEW MACROCYCLIC DIACID WITH BALANCED CONFORMATIONAL FLEXIBILITY AND PREORGANIZATION
Gennari, Cesare,Molinari, Francesco,Bartoletti, Marcella,Potenza, Donatella
, p. 279 - 282 (2007/10/02)
Macrocyclic diacid 1 was designed and synthesized as an effective catalyst for hemiacetal cleavage.Molecular modelling studies (using Clark Still's MacroModel) show that 1 has many accessible low energy conformations with various degrees of carboxyl group
Acceleration of Hemiacetal Cleavage through Hydrogen Bonding: A New Synthetic Catalyst with Balanced Conformational Flexibility and Preorganization
Gennari, Cesare,Molinari, Francesco,Bartoletti, Marcella,Piarulli, Umberto,Potenza, Donatella
, p. 3201 - 3203 (2007/10/02)
Hemiacetal cleavage catalyst 1 was designed, synthesized, and shown to be effective in promoting glycolaldehyde dimer dissociation and tetramethylglucose mutarotation.
