145913-55-9Relevant academic research and scientific papers
REACTION BETWEEN ISOPRENE AND ANILINE ON COMPLEX PALLADIUM CATALYSTS
Petrushkina, E. A.,Zakharkin, L. I.
, p. 1392 - 1394 (2007/10/02)
Isoprene and aniline have been reacted on the catalytic Pd(acac)2-Ph3P to form a mixture of isomeric telomers: N-(dimethyloctadien-2,7-yl-1)anilines and N-(dimethyloctadien-1,7-yl-3)anilines but on the catalytic system Pd(acac)2-Ph3P-CF3COOH the main product is a mixture of N-(methylbuten-2-yl)aniline adducts.The reaction between N-methylaniline and isoprene on the latter catalyst also gives a mixture of N-methyl and N-(methylbuten-2-yl)aniline adducts.Keywords: catalytic telomerization, terpenoid anilines.
