14596-64-6Relevant academic research and scientific papers
Cerium metal-mediated Reformatsky-type reaction with ethyl bromosuccinate for the synthesis of novel paraconic acid analogs
Rodrigues, Shirley M. M.,Nardini, Viviani,Constantino, Mauricio G.,Da Silva, Gil Valdo J.
supporting information, p. 6136 - 6137,2 (2020/08/20)
The treatment of cerium metal with ethyl bromosuccinate (1) forms the stabilized organolanthanoid intermediate (2), which reacts with carbonyl compounds in a Reformatsky-type reaction, under mild conditions, to produce functionalized γ-substituted paraconic acids (4) in good yields.
The Oxidation of 3,3-Diphenyl-2-propenoic Acid with Manganese(III) Acetate
Kurosawa, Kazu,Tsujita, Tsuyoshi
, p. 2391 - 2394 (2007/10/02)
The oxidation of 3,3-diphenyl-2-propenoic acid with manganese(III) acetate in boiling acetic gave 3,3-diphenyl-2-propenyl acetate, 4-acetoxymethyl-5,5-diphenyltetrahydro-2-furanone, 3,3-diphenyl-2-propenal, 5,5-diphenyl-2,5-dihydro-2-furanone, 4-acetoxy-5,5-diphenyltetrahydro-2-furanone, benzophenone, and 2-oxo-5,5-diphenyltetrahydro-4-furancarboxylic acid.The reaction pathways are discussed.
