1460293-45-1

Basic information

• Product Name: (4S)-4-((1,3-dithian-2-yl)methyl)-2-(4-methoxyphenyl)-1,3-dioxane
• Synonyms: (4S)-4-((1,3-dithian-2-yl)methyl)-2-(4-methoxyphenyl)-1,3-dioxane
• CAS NO: 1460293-45-1
• Molecular Weight: 326.481
• Mol File: 1460293-45-1.mol

Chemical Properties

• CAS DataBase Reference: (4S)-4-((1,3-dithian-2-yl)methyl)-2-(4-methoxyphenyl)-1,3-dioxane(CAS DataBase Reference)
• NIST Chemistry Reference: (4S)-4-((1,3-dithian-2-yl)methyl)-2-(4-methoxyphenyl)-1,3-dioxane(1460293-45-1)
• EPA Substance Registry System: (4S)-4-((1,3-dithian-2-yl)methyl)-2-(4-methoxyphenyl)-1,3-dioxane(1460293-45-1)

Safety Data

• Hazardous Substances Data: 1460293-45-1(Hazardous Substances Data)

Upstream product

• 103708-37-8 (2S,4S)-4-hydroxymethyl-2-(p-methoxymethyl)-1,3-dioxane 
• 505-23-7 1,3 dithiane 
• 1460293-44-0 (4S)-4-(iodomethyl)-2-(4-methoxyphenyl)-1,3-dioxane 

Downstream Products

• 1460293-46-2 (S)-4-(1,3-dithian-2-yl)-3-((4-methoxybenzyl)oxy)butan-1-ol 
• 1460293-59-7 (10S,E)-11-(2-((S)-4-((tert-butyldimethylsilyl)oxy)-2-((4-methoxybenzyl)oxy)butyl)-1,3-dithian-2-yl)-11-hydroxy-10-methylundec-7-en-1-yl pivalate 
• 1460293-60-0 (10S,E)-11-(2-((S)-4-((tert-butyldimethylsilyl)oxy)-2-((4-methoxybenzyl)oxy)butyl)-1,3-dithian-2-yl)-11-hydroxy-10-methylundec-7-en-1-yl pivalate 
• 1460293-48-4 (10S,11R,14S,E)-16-((tert-butyldimethylsilyl)oxy)-11-hydroxy-14-((4-methoxybenzyl)oxy)-10-methyl-12-oxohexadec-7-en-1-yl pivalate 
• 1460293-49-5 (S,E)-10-((4R,5S)-5-((S)-4-((tert-butyldimethylsilyl)oxy)-2-((4-methoxybenzyl)oxy)butyl)-2,2-dimethyl-1,3-dioxolan-4-yl)undec-7-en-1-yl pivalate 
• 1460293-53-1 C₃₆H₆₄O₇Si 
• 1460293-51-9 6-((4S,5S)-5-((S)-2-((4R,5S)-5-((S)-4-((tert-butyldimethylsilyl)-oxy)-2-((4-methoxybenzyl)oxy)butyl)-2,2-dimethyl-1,3-dioxolan-4-yl)propyl)-2,2-dimethyl-1,3-dioxolan-4-yl)hexyl pivalate 
• 1460293-50-8 (7S,8S,10S)-10-((4R,5S)-5-((S)-4-((tert-butyldimethylsilyl)oxy)-2-((4-methoxybenzyl)oxy)butyl)-2,2-dimethyl-1,3-dioxolan-4-yl)-7,8-dihydroxyundecyl pivalate 

Relevant articles and documents

Diastereoselective synthesis of the C14-C29 fragment of amphidinol 3

An efficient stereoselective synthesis of the C14-C29 fragment highlighting a coupling reaction between a 1,3-dithiane derivative and an α-branched aldehyde was realized. This highly convergent synthesis involved two chiral pools, l-malic acid and (+)-camphorsulfonic acid, which are the starting compounds to control the six stereogenic centers present in the C14-C29 fragment of amphidinol 3.