146053-93-2Relevant academic research and scientific papers
Synthesis and characterization of a series of mononuclear tantalum(V) hydride compounds containing aryloxide ligation
Parkin, Bernardeta C.,Clark, Janet R.,Visciglio, Valerie M.,Fanwick, Phillip E.,Rothwell, Ian P.
, p. 3002 - 3013 (2008/10/09)
A series of seven-coordinate, mononuclear tantalum-hydride compounds [Ta(OC6H3Pri2-2,6) 2-(Cl)3-n(H)n] (1, n = 1; 2, n = 2; 3, n = 3; OC6H3Prisu
Crystal and Molecular Structure of i2-2,6)3(PMe2Ph)>; a Distorted Six-coordinate Tantalum Dihydride
Visciglio, Valerie M.,Fanwick, Phillip E.,Rothwell, Ian P.
, p. 1505 - 1507 (2007/10/02)
Reaction of i2-2,6)3R2> (R = CH2C6H4-4-Me) with H2 in the presence of phosphine ligands (L) leads to the dihydride compounds i2-2,6)3(L)>, the solid-state structure of the PMe2Ph derivative shows a geometry about the metal centre that is severely distorted from octahedral; hydrogenation of aryl-phosphines and other aromatic substrates is catalysed by these dihydride compounds.
