1462235-94-4

Basic information

• Product Name: tert-butyl ethyl(4-methoxybenzyl)carbamate
• Synonyms: tert-butyl ethyl(4-methoxybenzyl)carbamate
• CAS NO: 1462235-94-4
• Molecular Weight: 265.353
• Mol File: 1462235-94-4.mol

Chemical Properties

• CAS DataBase Reference: tert-butyl ethyl(4-methoxybenzyl)carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl ethyl(4-methoxybenzyl)carbamate(1462235-94-4)
• EPA Substance Registry System: tert-butyl ethyl(4-methoxybenzyl)carbamate(1462235-94-4)

Safety Data

• Hazardous Substances Data: 1462235-94-4(Hazardous Substances Data)

Upstream product

• 34619-03-9 tert-butyldicarbonate 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 123387-71-3 tert-butyl ethyl(methyl)carbamate 
• 7541-17-5 tert-butyl N,N-dimethylcarbamate 

Relevant articles and documents

Ligand-controlled α- And β-arylation of acyclic N-boc amines

The palladium-catalyzed ligand-controlled arylation of α-zincated acyclic amines, obtained by directed α-lithiation and transmetalation, is described. Whereas PtBu3 gave rise to α-arylated Boc-protected amines, more flexible N-phenylazole-based phosphine ligands induced major β-arylation through migrative cross-coupling. All manner of control: The arylation of α-zincated acyclic Boc-protected amines was selectively performed at the α- or β-position in a ligand-controlled manner. α-Arylation occurs by direct reductive elimination of the α-palladated intermediate whereas β-arylation involves palladium migration along the alkyl chain. Boc=tert-butoxycarbonyl.