1462237-53-1

Basic information

• Product Name: C₇H₁₃BO₄
• CAS NO: 1462237-53-1
• Molecular Weight: 171.989
• Mol File: 1462237-53-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₇H₁₃BO₄(CAS DataBase Reference)
• NIST Chemistry Reference: C₇H₁₃BO₄(1462237-53-1)
• EPA Substance Registry System: C₇H₁₃BO₄(1462237-53-1)

Safety Data

• Hazardous Substances Data: 1462237-53-1(Hazardous Substances Data)

Upstream product

• 1111-72-4 carbon dioxide 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 

Relevant articles and documents

Carbene-9-BBN ring expansions as a route to intramolecular frustrated lewis pairs for CO2 reduction

Reactions of phosphine-derived carbenes with 9-borabicyclo[3.3.1]nonane (9-BBN) result in ring-expansion reactions to generate novel intramolecular frustrated Lewis pairs (FLPs). These FLPs effect the catalytic reduction of CO2 in the presence of boranes to give BOB and methoxy-borate species. A BOB well done: Reactions of phosphine-derived carbenes with 9-borabicyclo[3.3.1]nonane (9-BBN) result in ring-expansion reactions to generate novel intramolecular frustrated Lewis pairs (FLPs). These FLPs effect the catalytic reduction of CO2 in the presence of boranes to give BOB and methoxy-borate species (see scheme).