146232-38-4Relevant academic research and scientific papers
A novel method for generation of carbenoid from α-chloro sulfoxides: A new and versatile procedure for one-carbon homologation of carbonyl compounds to carbonyl compounds having an α-alkyl substituent
Satoh, Tsuyoshi,Itoh, Norifumi,Gengyo, Kaoru,Yamakawa, Koji
, p. 7543 - 7546 (1992)
Addition of the carbanion of 1-chloroalkyl p-tolyl sulfoxides to carbonyl compound gave the adducts, which were treated with a base followed by t-butyllithium to afford one-carbon homologated carbonyl compounds having an alkyl group at the α-position, via the β-oxido carbenoids, in moderate to good yields.
