146303-71-1Relevant articles and documents
PRODUCTION, PROPERTIES, AND MASS-SPECTROMETRIC INVESTIGATION OF THE DABSYLATES OF PHENOLS
Dem'yanov, P. I.,Khimenes, M. P.,Bogdashkina, V. I.,Petrosyan, V. S.
, p. 767 - 777 (2007/10/02)
The reaction of monohydric and dihydric phenols and phloroglucinol with 4'-(dimethylamino)azobenzene-4-sulfonyl chloride (dabsyl chloride) leads to the respective mono-, di-, and triabsylates of the phenols.Their structures were confirmed by IR, PMR, and mass spectrometry.A scheme is proposed for the dissociation of the phenol dabsylates under electron impact.The transformation of the phenols into the derivatives by reaction with dabsyl chloride is recommended for highly sensitive and selective determination of the individual phenols by high-performance liquid chromat ography with spectrophotometric detection and for spectrophotometric determination of total phenol content.