146329-35-3Relevant academic research and scientific papers
Synthesis of (-)-Talaromycin A. The use of the Δ2 effect for stereocontrol at spiroacetalic centres
Redlich,Lenfers,Thormahlen
, p. 1112 - 1118 (2007/10/02)
The new concept for stereocontrol at a spiroacetalic centre in thermodynamically controlled spiroacetalization, based on the operation of the Δ2 effect, allows the synthesis of (-)-Talaromycin A {(3R,4S,6R,9R)-9-ethyl-4-hydroxy-3-hydroxymethyl-1,7-dioxasp
