146335-12-8

Basic information

• Product Name: Benzoic acid, 2-[(methoxymethyl)thio]-, methyl ester
• CAS NO: 146335-12-8
• Molecular Formula: C10H12O3S
• Molecular Weight: 212.269
• Mol File: 146335-12-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 2-[(methoxymethyl)thio]-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 2-[(methoxymethyl)thio]-, methyl ester(146335-12-8)
• EPA Substance Registry System: Benzoic acid, 2-[(methoxymethyl)thio]-, methyl ester(146335-12-8)

Safety Data

• Hazardous Substances Data: 146335-12-8(Hazardous Substances Data)

Upstream product

• 13057-19-7 Iodomethyl methyl ether 
• 4892-02-8 Methyl thiosalicylate 
• 146335-10-6 1-bromo-2-<(methoxymethyl)thio>benzene 
• 79-22-1 methyl chloroformate 

Downstream Products

• 90536-67-7 2-(methoxysulfinyl)benzoic acid methyl ester 
• 26638-43-7 2-methoxycarbonylbenzenesulfonyl chloride 

Relevant articles and documents

Oxidation of aromatic lithium thiolates into sulfinate salts: An attractive entry to aryl sulfones labeled with carbon-11

Aromatic 11C-sulfones were synthesized by S alkylation of lithium arenesulfinates, which are readily available from the corresponding thiols by an oxaziridine-mediated oxidation reaction with [11C]alkyl iodides in THF/H2O (4:1) at 150 °C. The radiosyntheses, including purification by HPLC, were completed in an average of 35 min from the end of the bombardment with 55-76% overall radiochemical yields (decay corrected). The described procedure extends the range of accessible labeling methods.