1463469-25-1

Basic information

• Product Name: N-[(9H-fluoren-9-ylmethoxy)carbonyl]-O-(4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-L-serine phenylmethyl ester
• Synonyms: N-[(9H-fluoren-9-ylmethoxy)carbonyl]-O-(4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-L-serine phenylmethyl ester
• CAS NO: 1463469-25-1
• Molecular Weight: 629.664
• Mol File: 1463469-25-1.mol

Chemical Properties

• CAS DataBase Reference: N-[(9H-fluoren-9-ylmethoxy)carbonyl]-O-(4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-L-serine phenylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N-[(9H-fluoren-9-ylmethoxy)carbonyl]-O-(4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-L-serine phenylmethyl ester(1463469-25-1)
• EPA Substance Registry System: N-[(9H-fluoren-9-ylmethoxy)carbonyl]-O-(4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl)-L-serine phenylmethyl ester(1463469-25-1)

Safety Data

• Hazardous Substances Data: 1463469-25-1(Hazardous Substances Data)

Upstream product

• 118358-66-0 N-(9-fluorenylmethyloxycarbonyl)-L-serine benzyl ester 
• 2873-29-2 D-glucal triacetate 

Relevant articles and documents

Hafnium(IV) triflate as a highly efficient catalyst for Ferrier rearrangement of O- and S-nucleophiles with glycals

A highly efficient method to afford 2,3-unsaturated glycosides was described. In the presence of Hafnium(IV) triflate, a variety of 2,3-unsaturated-O- and S-glycosides have been obtained by stereoselective glycosylation of 3,4,6-tri-O-acetyl-d-glucal and hexa-O-acetyl-d-lactal with various acceptors in good isolated yields.

I2-mediated α-selective Ferrier glycosylation approach to synthesis of O-glycosyl amino acids

I2 is an effective promoter for the synthesis of 2,3-unsaturated glycosides via Ferrier glycosylation. This reaction was used in the present work for the synthesis of O-glycosylated Fmoc amino acid building blocks. This metal-free reaction affo