146347-17-3Relevant academic research and scientific papers
DARSTELLUNG UND ELEKTROCHEMISCHE REDUKTION NITROSUBSTITUIERTER ALKANDITHIOSAEURE-METHYLESTER
Wollny, Bernd,Voss, Juergen
, p. 231 - 244 (2007/10/02)
Methyl nitroalkanedithioates 3 were prepared from the corresponding carboxylic acids 1 and Davy's reagent 2 or, 3e, from 2-nitro-propane, carbon disulfide and iodomethane.Electrochemical reduction of these dithioesters leads to ketene S,S-acetals 4 and oximes 5.In addition, carboxylic oximes 6 are formed.The latter and related elimination products 14 are also obtained by conventional routes.Key words: Methyl nitroalkanedithioates; polarography; cyclovoltammetry; preparative electroreduction; intramolecular cyclization.
