1464149-44-7

Basic information

• Product Name: (E)-(3-(4-(tert-butyl)phenyl)allyl)(trifluoromethyl)sulfane
• Synonyms: (E)-(3-(4-(tert-butyl)phenyl)allyl)(trifluoromethyl)sulfane
• CAS NO: 1464149-44-7
• Molecular Weight: 274.35
• Mol File: 1464149-44-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (E)-(3-(4-(tert-butyl)phenyl)allyl)(trifluoromethyl)sulfane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(3-(4-(tert-butyl)phenyl)allyl)(trifluoromethyl)sulfane(1464149-44-7)
• EPA Substance Registry System: (E)-(3-(4-(tert-butyl)phenyl)allyl)(trifluoromethyl)sulfane(1464149-44-7)

Safety Data

• Hazardous Substances Data: 1464149-44-7(Hazardous Substances Data)

Upstream product

• 335314-71-1 1-(4-t-butylphenyl)-prop-2-enyl methyl carbonate 
• 81290-20-2 (trifluoromethyl)trimethylsilane 
• 149169-92-6 (E)-1-(3-bromoprop-1-en-1-yl)-4-(tert-butyl)benzene 

Relevant articles and documents

Ruthenium-catalyzed regioselective allylic trifluoromethylthiolation reaction

An efficient Ru-catalyzed regioselective allylic trifluoromethylthiolation reaction of allylic carbonates was developed. The linear allylic trifluoromethyl thioethers were obtained in 52-91% yields. Mechanistic investigation revealed that this reaction proceeds via a double allylic trifluoromethylthiolation sequence.

Copper(I) trifluoromethylthiolate complex bearing triphenylphosphine ligand for nucleophilic trifluoromethylthiolation of allylic bromides

Copper(I) trifluoromethylthiolate complex (PPh3) 2Cu(SCF3) (1) has been synthesized from a convenient reaction of CuF2 with CF3SiMe3 and S 8 in the presence of triphenylphosphine. The crystal structure of complex 1 has been determined by X-ray crystallography. In the solid state, complex 1 exists as a monomeric copper(I) species with a three-coordinated trigonal planar geometry. Complex 1 reacted with a wide range of allylic bromides to afford corresponding allylic trifluoromethyl thioethers in moderate to good yields. Several functional groups, including alkyl, alkoxy, nitro, halides and geranyl groups, are tolerated.