146464-97-3Relevant academic research and scientific papers
Synthesis and applications of α-trifluoromethylated alkylboron compounds
Argintaru, O. Andreea,Ryu, Daweon,Aron, Ioana,Molander, Gary A.
, p. 13656 - 13660 (2013)
RBF3K is a chemist's BFF: A metal-free synthetic route to unprecedented organoboron compounds bearing an α-trifluoromethyl substituent, employing a variety of trifluoroborate (RBF3K) starting materials, is reported. These substrates represent the first isolated α-trifluoromethylated alkylboron building blocks, and these reagents lead to a variety of useful bench-stable, synthetic intermediates. Pin=pinacol. Copyright
SYNTHESIS AND USE OF FLUORINATED COMPOUNDS
-
Paragraph 0163; 0164, (2014/09/03)
The invention is directed to the preparation of fluorinated compounds and their use in organic synthesis. In particular, the invention is directed to methods of reacting compounds of structure with Rf-CH=N2 or (CF3)2C=N2 to form a perfluoroalkylate or -arylated compounds, and products derived from these reactions, where X, YB, and Rf are described herein.
Synthesis and Properties of Optically Active α-Trifluoromethylbenzyl Derivatives as New Chiral Dopants for Ferroelectric Liquid Crystals
Aoki, Yoshio,Nohira, Hiroyuki
, p. 113 - 116 (2007/10/02)
Optically active α-trifluoromethylbenzyl derivatives as new chiral dopants for ferroelectric liquid crystals (FLCs) were synthesized utilizing optically active 4,4,4-trifluoro-3-(4-methoxyphenyl)butanoic acid prepared by optical resolution procedures.The
