1464782-28-2Relevant articles and documents
Asymmetric formation of tert-alkylamines from serinols by a dual function catalyst
You, Young Suk,Kim, Tae Woo,Kang, Sung Ho
, p. 9669 - 9671 (2013/10/08)
Consecutive intramolecular desymmetrization and kinetic resolution of 2-substituted N-phenoxycarbonylserinols have been achieved in one-pot by a single chiral catalyst, bisox(7)-CuCl2, to form oxazolidinones with remarkable enantioselectivities (94-99% ee) as tert-alkylamine building blocks. The process culminates in a dual-function of the chiral catalyst. The Royal Society of Chemistry 2013.