146495-24-1

Basic information

• Product Name: Acetonitrile, [(diphenylmethyl)amino]-
• CAS NO: 146495-24-1
• Molecular Formula: C15H14N2
• Molecular Weight: 222.29
• Mol File: 146495-24-1.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Acetonitrile, [(diphenylmethyl)amino]-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetonitrile, [(diphenylmethyl)amino]-(146495-24-1)
• EPA Substance Registry System: Acetonitrile, [(diphenylmethyl)amino]-(146495-24-1)

Safety Data

• Hazardous Substances Data: 146495-24-1(Hazardous Substances Data)

Upstream product

• 40569-56-0 N-benzhydryl-3-(hydroxyimino)azetidine 
• 40320-60-3 N-benzhydryl 3-azetidinone 
• 20771-60-2 2-methoxyphenyl isocyanide 
• 7175-47-5 4-methylphenyl isocyanide 
• 134420-06-7 p-ethoxy phenyl isonitrile 
• 10349-38-9 p-methoxyphenylisonitrile 
• 62-53-3 aniline 
• 1885-81-0 p-chlorophenyl isocyanide 
• 119072-54-7 2,6-dimethylphenyl isonitrile 
• 88333-03-3 Benzyl isocyanide 
• 2769-64-4 n-butyl isonitrile 
• 931-53-3 Cyclohexyl isocyanide 
• 119072-55-8 tert-butylisonitrile 

Downstream Products

• 1416475-89-2 (E)-N-(1-ethoxy-1-oxopropan-2-ylidene)-1,1-diphenylmethanamine oxide 
• 1416475-87-0 (E)-N-(1,4-dimethoxy-1,4-dioxobutan-2-ylidene)-1,1-diphenylmethanamine oxide 
• 1416476-05-5 (3R,4S,5R)-ethyl 2-benzhydryl-4-formyl-3,5-dimethylisoxazolidine-3-carboxylate 
• 1416476-06-6 (3S,4S,5R)-ethyl 2-benzhydryl-4-formyl-3,5-dimethylisoxazolidine-3-carboxylate 
• 137283-20-6 2-(Benzhydrylidene-amino)-hexanenitrile 
• 70591-21-8 C₁₆H₁₄N₂ 
• 86-29-3 Diphenylacetonitrile 
• 566202-63-9 (3S,4R,5R)-N-diphenylhydroxymethyl-3-(1'-hydroxyethyl)-4-cyanoazetidin-2-one 
• 566202-62-8 (3S,4S,5R)-N-diphenylhydroxymethyl-3-(1'-hydroxyethyl)-4-cyanoazetidin-2-one 
• 566202-60-6 (3S,4R,5R)-N-(diphenylmethyl)-3-(1'-hydroxyethyl)-4-cyanoazetidin-2-one 
• 566202-59-3 (3S,4S,5R)-N-(diphenylmethyl)-3-(1'-hydroxyethyl)-4-cyanoazetidin-2-one 
• 1485-71-8 benzophenone oxime 

Relevant articles and documents

Dynamics in Catalytic Asymmetric Diastereoconvergent (3 + 2) Cycloadditions with Isomerizable Nitrones and α-Keto Ester Enolates

Reaction design in asymmetric catalysis has traditionally been predicated on a structurally robust scaffold in both substrates and catalysts, to reduce the number of possible diastereomeric transition states. Herein, we present the stereochemical dynamics in the Ni(II)-catalyzed diastereoconvergent (3 + 2) cycloadditions of isomerizable nitrile-conjugated nitrones with α-keto ester enolates. Even in the presence of multiple equilibrating species, the catalytic protocol displays a wide substrate scope to access a range of CN-containing building blocks bearing adjacent stereocenters with high enantio- and diastereoselectivities. Our computational investigations suggest that the enantioselectivity is governed in the deprotonation process to form (Z)-Ni-enolates, while the unique syn addition is mainly controlled by weak noncovalent bonding interactions between the nitrone and ligand.

Organocatalytic enantio- and diastereoselective 1,3-dipolar cycloaddition between alanine-derived ketonitrones and E-crotonaldehyde: Efficiency and full stereochemical studies

Highly enantio- and exo-selective 1,3-dipolar cycloadditions of alanine-derived ketonitrones to E-crotonaldehyde could be realized in a good yield by the use of a chiral imidazolidinone salt without the addition of water. The origin of the stereoselectivi

Photoreduction of imines. An environmentally friendly approach to obtain amines

The photoreduction of different imines to amines in alcoholic solvents is reported. The reduction involves a versatile and chemoselective methodology that is environmentally friendly in that it avoids the use of metal hydrides and other dangerous reducing agents.