146499-02-7

Upstream product

• 150763-52-3 (1'S,4a'S,8a'S)-4-methoxy-2-(1'-methyl-8'-oxodecahydronaphthalen-1'-yl)benzaldehyde 
• 917-64-6 methyl magnesium iodide 
• 146499-04-9 (1'R,4a'S,8'S,8a'S)-8'-(5''-methoxy-2''-methylphenyl)-8'-methyldecahydronaphthalen-1'-yl 2-oxophenylacetate 

Downstream Products

• 155085-50-0 (1'R,4a'S,8'S,8a'S)-8'-(5''-methoxy-2''-methylphenyl)-8'-methyldecahydronaphthalen-1'-yl 3-oxobutanoate 
• 146499-03-8 (1'R,4a'S,8'S,8a'S)-8'-(5''-methoxy-2''-methylphenyl)-8'-methyldecahydronaphthalen-1'-yl prop-2-enoate 
• 155085-51-1 (1'R,4a'S,8'S,8a'S)-8'-(5''-methoxy-2''-methylphenyl)-8'-methyldecahydronaphthalen-1'-yl (Z)-3-acetamido-2-butenoate 
• 146499-04-9 (1'R,4a'S,8'S,8a'S)-8'-(5''-methoxy-2''-methylphenyl)-8'-methyldecahydronaphthalen-1'-yl 2-oxophenylacetate 

Relevant academic research and scientific papers

The Synthesis of an Arylperhydronaphthalenol, an Efficient Chiral Auxiliary

The synthesis of (1R,4aS,8S,8aS)-8-(5'-methoxy-2'-methylphenyl)-8-methyldecahydronaphthalen-1-ol from podocarpic acid is described.

Asymmetric syntheses with a new optically active perhydronaphthalene based chiral auxiliary

(1R,4aS,8S,8aS)-8-(5'-Methoxy-2'-methylphenyl)-8-methyldecahydro-1-nap hthalenol 3a is a highly efficient chiral auxiliary in the Diels-Alder addition of its acrylate ester 5 and in the DIBAL-H and Grignard reactions of its phenylglyoxylate ester 7.