146581-82-0

Basic information

• Product Name: 2,2'-BIPYRIDINE-4-CARBALDEHYDE
• Synonyms: 2,2'-BIPYRIDINE-4-CARBALDEHYDE;2-pyridin-2-ylpyridine-4-carbaldehyde;2,2'-bipyridine-4-carboxaldehyde
• CAS NO: 146581-82-0
• Molecular Formula: C₁₁H₈N₂O
• Molecular Weight: 184.19
• Mol File: 146581-82-0.mol
• Article Data: 3

Chemical Properties

• Melting Point: 94-95 °C(Solv: hexane (110-54-3))
• Boiling Point: 361.3±32.0 °C(Predicted)
• Appearance: /
• Density: 1.205±0.06 g/cm3(Predicted)
• PKA: 3.74±0.22(Predicted)
• CAS DataBase Reference: 2,2'-BIPYRIDINE-4-CARBALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2'-BIPYRIDINE-4-CARBALDEHYDE(146581-82-0)
• EPA Substance Registry System: 2,2'-BIPYRIDINE-4-CARBALDEHYDE(146581-82-0)

Safety Data

• Hazardous Substances Data: 146581-82-0(Hazardous Substances Data)

Usage

General Description

2,2'-BIPYRIDINE-4-CARBALDEHYDE is a chemical compound with the molecular formula C12H8N2O. It is a derivative of bipyridine and is commonly used as a ligand in coordination chemistry and catalysis. 2,2'-BIPYRIDINE-4-CARBALDEHYDE is known for its ability to form stable and selective metal complexes, making it a valuable tool in various chemical reactions and industrial processes. 2,2'-BIPYRIDINE-4-CARBALDEHYDE has also been studied for its potential applications in organic synthesis and material science. Its unique structure and reactivity make it a versatile and important compound in the field of chemistry.

Upstream product

• 56100-19-7 4-methyl-2,2'-bipyridine 
• 366-18-7 [2,2]bipyridinyl 
• 14163-00-9 4-nitro-2,2'-bipyridine N-oxide 
• 33421-43-1 2,2'-bipyridyl N-oxide 
• 68-12-2 N,N-dimethyl-formamide 
• 14162-95-9 4-bromo-2,2'-bipyridyl 
• 26482-00-8 1-(2-oxo-2-(2-pyridyl)ethyl)pyridinium iodide 

Downstream Products

• 896732-96-0 4-[bis-(4-prop-2-ynyloxy-phenyl)-methyl]-[2,2']bipyridinyl 

Relevant articles and documents

Electrochemical probing of ground state electronic interactions in polynuclear complexes of a new heteroditopic ligand

The synthesis and electronic properties of dinuclear ([(bipy) 2Ru(I)M(terpy)][PF6]4 (bipy = 2,2′-bipyridine, terpy = 2,2′:6′,2″-terpyridine; M = Ru, Os)) and trinuclear ([{(bipy)2Ru(I)}2M][PF6]6 M = Ru, Os, Fe, Co) complexes bridged by 4′-(2,2′-bipyridin-4-yl)-2,2′:6′, 2″-terpyridine (I) have been investigated and are compared with those of mononuclear model complexes. The electrochemical analysis using cyclic voltammetry and differential pulse voltammetry reveals that there are no interactions in the ground state between adjacent metal centres. However, there is strong electronic communication between the 2,2′-bipyridine and 2,2′:6′,2″-terpyridine components of the bridging ligand. This conclusion is supported by a step-by-step reduction of the dinuclear and trinuclear complexes and the assignment of each electrochemical process to localised ligand sites within the didentate and terdentate domains. The investigation of the electronic absorption and emission spectra reveals an energy transfer in the excited state from the terminating bipy-bound metal centres to the central terpy-bound metal centre. This indicates that the bridge is able to facilitate energy transfer in the excited state between the metal centres despite the lack of interactions in the ground state.

Chemoenzymatic Synthesis of 2-Amino-3-(2,2'-bipyridinyl)propanoic Acids

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