14659-62-2Relevant academic research and scientific papers
PHOTOCHEMISTRY OF 3-ARYL-2-ISOXAZOLINE
Kumagai, T.,Shimizu, K.,Kawamura, Y.,Mukai, T.
, p. 3365 - 3376 (2007/10/02)
3-Phenyl-2-isoxazoline (1) was irradiated to give 4-phenyl-2-oxazoline (3), β-aminoaldehyde (14) and benzonitrile from its ?-?* singlet excited state.Several related derivatives afforded similar photoproducts on irradiation.The quantum yields of the photoreactions were dependent on the magnitudes of the singlet energies of the 2-isoxazolines. p-Cyanophenyl-2-isoxaline (1c) formed a one-to-one photoadduct (22) with benzene.
