146601-32-3Relevant articles and documents
New, Chiral Silylated Organophosphorus(III) Reagents: Syntheses and Applications in the Asymmetric Phosphorylation of Aldehydes
Sum, Vivienne,Davies, Anita J.,Kee, Terence P.
, p. 1771 - 1773 (2007/10/02)
The new silylated organophosphorus(III) compounds, (1R,2S)-(O,N-ephedrine)POSiR3 (R3=Ph3, t-BuMe2, Et3) have been synthesised and shown to react with benzaldehyde to afford the phosphonate esters (1R,2S)-(O,N-ephedrine)P(=O)CHPh(OSiR3) with good stereosel