146643-79-0Relevant academic research and scientific papers
N-Chlorosuccinimide promoted direct C(sp2)–H bond thiolation of the methoxybenzenes with thiophenols
Raghavender Reddy,Kumar, G. Santosh,Meshram
supporting information, p. 3622 - 3624 (2016/07/22)
A simple and an efficient procedure for the formation of diaryl sulfides via direct sp2C–H functionalization have been developed from simple and readily available thiophenols and substituted methoxy benzenes. In this process thiophenols were us
Bis(2-pyridyl)diselenoethers as versatile ligands for copper-catalyzed C-S bond formation in glycerol
Cargnelutti, Roberta,Lang, Ernesto S.,Schumacher, Ricardo F.
supporting information, p. 5218 - 5222 (2015/08/19)
In this Letter, we describe a simple and efficient general methodology for CuI/bis(2-pyridyl)diselenoether-catalyzed C-S coupling reactions of aryl halides with thiols using glycerol as an environmentally friendly solvent. The products were obtained in moderate to excellent yields. The performance of CuI/L3-catalyzed C-S coupling reactions in glycerol is comparable to the related cross-coupling reactions in common organic solvents using transition-metal salts as catalyst. The use of the system CuI/L3/glycerol related in this work offers the possibility of performing the reaction in the absence of toxic organic solvents, expensive metals and using ultrasound as an alternative energy source.
Metal complexes with bis(2-pyridyl)diselenoethers: Structural chemistry and catalysis
Cargnelutti, Roberta,Da Silva, Felipe Dornelles,Abram, Ulrich,Lang, Ernesto Schulz
, p. 7948 - 7953 (2015/10/12)
Bis(2-pyridyl)diselenoethers with the general formula (2-PySe)2(CH2)n [n = 1, 3 and 4] react with CuI, AgNO3, CuCl2·2H2O and CoCl2·6H2O resulting in the formation of p
Carbon-sulfur bond formation catalyzed by [Pd(IPr*OMe) (cin)Cl] (cin = cinnamyl)
Bastug, Gulluzar,Nolan, Steven P.
supporting information, p. 9303 - 9308 (2013/10/08)
The newly prepared complex [Pd(IPr*OMe)(cin)(Cl)] provides high catalytic activity for carbon-sulfur cross-coupling reactions. Nonactivated and deactivated aryl halides were successfully coupled with a large variety of aryl- and alkylthiols using this well-defined palladium N-heterocyclic carbene (NHC) complex.
Formation of carbon-sulfur and carbon-selenium bonds by palladium-catalyzed decarboxylative cross-couplings of hindered 2,6-dialkoxybenzoic acids
Becht, Jean-Michel,Le Drian, Claude
experimental part, p. 6327 - 6330 (2011/10/05)
A simple route to diaryl sulfides using a decarboxylative palladium-catalyzed reaction between electron-rich 2,6-dialkoxybenzoic acid derivatives and diaryl disulfides is reported. This coupling proceeds efficiently in the presence of Pd(CF3CO
