146821-00-3

Basic information

• Product Name: (2R,3S,4R,5S)-4-Acetoxy-5-azido-3-iodo-2-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester
• Synonyms: (2R,3S,4R,5S)-4-Acetoxy-5-azido-3-iodo-2-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester
• CAS NO: 146821-00-3
• Molecular Weight: 831.658
• Mol File: 146821-00-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,3S,4R,5S)-4-Acetoxy-5-azido-3-iodo-2-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S,4R,5S)-4-Acetoxy-5-azido-3-iodo-2-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester(146821-00-3)
• EPA Substance Registry System: (2R,3S,4R,5S)-4-Acetoxy-5-azido-3-iodo-2-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester(146821-00-3)

Safety Data

• Hazardous Substances Data: 146821-00-3(Hazardous Substances Data)

Upstream product

• 90-80-2 D-Glucono-1,5-lactone 
• 146820-93-1 (R)-((4R,5S,4'R)-2,2,2',2'-Tetramethyl-[4,4']bi[[1,3]dioxolanyl]-5-yl)-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-acetic acid methyl ester 
• 114743-85-0 methyl 3,4:5,6-di-O-isopropylidene-D-gluconate 
• 76679-47-5 methyl-2,3,4-tri-O-benzyl-6-O-trifluoromethanesulfonyl-α-D-glucopyranoside 
• 186581-53-3 diazomethane 
• 146820-98-6 Acetic acid (2R,3S,4R,5S)-5-azido-3-iodo-2-methylcarbamoyl-2-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-4-yl ester 

Downstream Products

• 149297-74-5 (2S,4S,5S)-4-Acetoxy-5-acetylamino-2-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 146821-01-4 Acetic acid (1S,4S,8S)-6-oxo-1-((2R,3R,4S,5R,6S)-3,4,5-tris-benzyloxy-6-methoxy-tetrahydro-pyran-2-ylmethoxy)-2-oxa-5-aza-bicyclo[2.2.2]oct-8-yl ester 

Relevant articles and documents

Highly stereoselective synthesis of α-glycosides of neuraminic acid analogues

ε-Hydroxy enol ether 6 was readily prepared from D-gluconolactone via ester formation and selective di-O-isopropylidenation, 2-O-alkylation with triflate 1, selective 5,6-de-O-isopropylidenation and 6-O-silylation, azide introduction, and subsequent E-spe