146860-48-2Relevant academic research and scientific papers
New Effective Catalysts for Mukaiyama-Aldol and -Michael Reactions: BiCl3 - Metallic Iodide Systems
Roux, Christophe Le,Gaspard-Iloughmane, Hafida,Dubac, Jacques,Jaud, Joel,Vignaux, Pierre
, p. 1835 - 1839 (1993)
Metallic iodide-activated bismuth(III) chloride efficiently catalyzes the Mukaiyama-Aldol and -Michael reactions.Some examples of reactions of silyl enol ethers derived from acetophenone and cyclohexanone (1 and 2, respectively) with aldehydes, ketones, a
Bismuth(III) Triflate: A Water-Stable Equivalent of Trimethylsilyl Triflate for the Catalysis of Mukaiyama Aldol Reactions
Roux, C. Le,Ciliberti, L.,Laurent-Robert, H.,Laporterie, A.,Dubac, J.
, p. 1249 - 1251 (2007/10/03)
Bismuth tris-trifluoromethanesulfonate (1) has been found to be an efficient catalyst for the Mukaiyama aldol-type reactions.The catalytic activity of this catalyst is higher than the one previously reported for the rare earth triflates M(OTf)3 (M = Sc, L
Bismuth Trichloride as a New Efficient Catalyst in the Aldol Reaction and the Michael Reaction
Wada, Makoto,Takeichi, Eiji,Matsumoto, Takashi
, p. 990 - 994 (2007/10/02)
In the presence of a catalytic amount of bismuth(III) trichloride (5 mol percent), silyl enol ethers react with aldehydes at room temperature in dichloromethane to give the corresponding aldols in good yields.Silyl enol ethers also have been found to reac
