146860-49-3Relevant academic research and scientific papers
BiCl3-catalyzed Mukaiyama-aldol and carbonyl-ene reactions
Peidro, Laurence,Le Roux, Christophe,Laporterie, Andre,Dubac, Jacques
, p. 397 - 399 (1996)
The H-ene pathway has not been detected for the bismuth(III) chloride-catalyzed Mukaiyama-aldol reaction involving silyl enol ethers and aldehydes. The silatropic ene-like process is the only mechanism observed, even with the weakly reactive 1-(trimethylsilyloxy) cyclohexene. However, trimerization of an aliphatic aldehyde can occur.
New Effective Catalysts for Mukaiyama-Aldol and -Michael Reactions: BiCl3 - Metallic Iodide Systems
Roux, Christophe Le,Gaspard-Iloughmane, Hafida,Dubac, Jacques,Jaud, Joel,Vignaux, Pierre
, p. 1835 - 1839 (2007/10/02)
Metallic iodide-activated bismuth(III) chloride efficiently catalyzes the Mukaiyama-Aldol and -Michael reactions.Some examples of reactions of silyl enol ethers derived from acetophenone and cyclohexanone (1 and 2, respectively) with aldehydes, ketones, a
