BiCl3-catalyzed Mukaiyama-aldol and carbonyl-ene reactions

DOI: 10.1016/0022-328X(96)06229-8

Source and publish data:

Journal of Organometallic Chemistry p. 397 - 399 (1996)

Update date:2022-08-04

Topics:

Authors:

Peidro, Laurence

Le Roux, Christophe

Laporterie, Andre

Dubac, Jacques

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Article abstract of DOI:10.1016/0022-328X(96)06229-8

The H-ene pathway has not been detected for the bismuth(III) chloride-catalyzed Mukaiyama-aldol reaction involving silyl enol ethers and aldehydes. The silatropic ene-like process is the only mechanism observed, even with the weakly reactive 1-(trimethylsilyloxy) cyclohexene. However, trimerization of an aliphatic aldehyde can occur.

Full text of DOI:10.1016/0022-328X(96)06229-8

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