Journal of Organometallic Chemistry p. 397 - 399 (1996)
Update date:2022-08-04
Topics:
Peidro, Laurence
Le Roux, Christophe
Laporterie, Andre
Dubac, Jacques
The H-ene pathway has not been detected for the bismuth(III) chloride-catalyzed Mukaiyama-aldol reaction involving silyl enol ethers and aldehydes. The silatropic ene-like process is the only mechanism observed, even with the weakly reactive 1-(trimethylsilyloxy) cyclohexene. However, trimerization of an aliphatic aldehyde can occur.
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