BiCl3-catalyzed Mukaiyama-aldol and carbonyl-ene reactions

DOI: 10.1016/0022-328X(96)06229-8

Source and publish data:

Journal of Organometallic Chemistry p. 397 - 399 (1996)

Update date:2022-08-04

Topics:

Authors:

Peidro, Laurence

Le Roux, Christophe

Laporterie, Andre

Dubac, Jacques

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(96)06229-8

The H-ene pathway has not been detected for the bismuth(III) chloride-catalyzed Mukaiyama-aldol reaction involving silyl enol ethers and aldehydes. The silatropic ene-like process is the only mechanism observed, even with the weakly reactive 1-(trimethylsilyloxy) cyclohexene. However, trimerization of an aliphatic aldehyde can occur.

Full text of DOI:10.1016/0022-328X(96)06229-8

Products guided by the article

Product name:2-(1-trimethylsiloxybutyl)-cyclohexanone

Cas No:146860-49-3

R&D Labs maybe for 146860-49-3

Laizhou City Laiyu Chemical CO.,Ltd

Contact:+86-535-2719337/2719339

Address:Chenggang road zhuyou laizhou City Shangdong China
Hunan Shineway Enterprise Co., Ltd.

Contact:+86-731-86303875

Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China
Valiant Fine Chemicals Co., Ltd.

Contact:+86 535 6101878/6374484

Address:11 Wuzhishan Rd.,YTETDZ,Yantai,264006,Shandong,China
Huayi Isotopes Co.

Contact:+ 86 512 52491118

Address:1 Fuyu Road, Haiyu TownChangshu, Jiangsu, China
Shaanxi King Stone Enterprise Company Limited

Contact:86-29-88353805,13609285751

Address:.209 Keji Road Hi-Tech industrial Develpment Zone .Xian China

Relevant to this article

Fluoride-induced chemiluminescent decomposition of 1,2-dioxetanes bearing a phenyl moiety substituted with a methyl having an electron-withdrawing group

Doi:10.1039/b210857g
(2003)
Three-dimensional six-connecting organic building blocks based on polychlorotriphenylmethyl units - Synthesis, self-assembly, and magnetic properties

Doi:10.1002/chem.200600447
(2006)
Linearly polarised organic light-emitting diodes (OLEDs): Synthesis and characterisation of a novel hole-transporting photoalignment copolymer

Doi:10.1039/b506063j
(2005)
Syntheses and characterization of cyano-bridged homo and hetero bimetallic complexes containing η⁵ and η⁶-cyclic hydrocarbons

Doi:10.1016/j.jorganchem.2005.05.044
(2005)
REACTIONS OF AZIRIDINE-2-CARBOXYLIC ACID DERIVATIVES WITH ESTERS AND NITRILES OF UNSATURATED ACIDS

Doi:10.1007/BF00516205
(1983)
A new heterospin complex from oxamide-bridged Cu(II) binuclear units and carboxy-phenyl-substituted nitronyl nitroxide

Doi:10.1016/j.inoche.2005.02.015
(2005)

Article Doi