146920-17-4Relevant academic research and scientific papers
NMR Studies of Hindered Rotation and Thermal Decomposition of Novel 1-Aryl-3,3-dialkyltriazenes
Lippert, Th.,Wokaun, A.,Dauth, J.,Nuyken, O.
, p. 1178 - 1185 (1992)
1-Aryl-3,3-dialkyltriazenes have been synthesized by coupling the corresponding diazonium salts of substituted aniline derivatives with dialkylamines.The thermostability of these compounds was investigated by differential scanning calorimetry; activation
Synthesis of Aryl Trimethylstannane via BF3·OEt2-Mediated Cross-Coupling of Hexaalkyl Distannane Reagent with Aryl Triazene at Room Temperature
Mao, Shuai,Chen, Zhengkai,Wang, Lu,Khadka, Daulat Bikram,Xin, Minhang,Li, Pengfei,Zhang, San-Qi
, p. 463 - 471 (2019/01/10)
BF3·OEt2-mediated cross-coupling of (SnMe3)2 with aryl triazene offers a new strategy for the synthesis of aryl stannane. A variety of synthetically useful aryl trimethylstannanes were produced in moderate to good yields with this metal-free approach. One-pot sequential Stille cross-coupling with different aryl bromides provides a short entry to both symmetrical and unsymmetrical biaryl compounds.
